📖 Dental Materials
PFM Alloys
Dental MaterialsPFM Alloys
Applications-substructures for porcelain-fused-to-metal crowns and bridges
Classification
o High-gold alloys
o Palladium-silver alloys
o Nickel-chromium alloys
Structure
Composition
o High-gold alloys are 98% gold. platinum. And palladium
o Palladium-silver alloys are 50% to 60% palladium and 30 to 40% silver
o Nickel-chromium alloys are 70% to 80% nickel and 15% chromium with other metals
Manipulation
o Must have melting temperatures above that of porcelains to be bonded to their surface
o More difficult to cast (see section on chromium alloys)
Properties - Physical
Except for high-gold alloys, others are less dense alloys
Alloys are designed to have low thermal expansion coefficients that must be matched to the overlying porcelain
Chemical-high-gold alloys are immune, but others passivate
Mechanical-high modulus and hardness
COMPOSITE RESINS - Properties
Dental MaterialsProperties-improve with filler content
Physical
Radiopacity depends on ions in silicate glass or the addition of barium sulfate (many systems radiolucent)
Coefficient of thermal expansion is 35 to 45 ppm/C and decreases with increasing filler content
Thermal and electrical insulators
Chemical
Water absorption is 0.5 % to 2.5% and increases with polymer level)
Acidulated topical fluorides (e.g., APF) tend to dissolve glass particles, and thus composites should be protected with petroleum jelly (Vaseline) during those procedures
Color changes occur in resin matrix with time because of oxidation, which produces colored by-products
Mechanical
Compressive strength is 45,000 to 60,000 lb/ in2, which is adequate
Wear resistance-improves with higher filler content, higher percentage of conversion in curing, and use of microfiller, but it is not adequate for some posterior applications
Surfaces rough from wear retain plaque and stain more readily
Biologic
Components may be cytotoxic, but cured composite is biocompatible as restorative filling material
Mercury hygiene
Dental MaterialsMercury hygiene
- Do not contact mercury with skin
- Clean up spills to minimize mercury vaporization
- Store mercury or precapsulated products in tight containers
- Only triturate amalgam components-in tightly- sealed capsules
- Use amalgam with covers
- Store spent amalgam under water or fixer in a tightly sealed jar
- Use high vacuum suction during amalgam alloy placement, setting, or removal when mercury may be vaporized
- Polishing amalgams generally causes localized melting of silver-mercury phase with release of mercury vapor, so water cooling and evacuation must be used
CRUCIBLE FORMER
Dental MaterialsCRUCIBLE FORMER
It serves as a base for the casting ring during investing .Usually convex in shape.
May be metal , plastic or rubber .
Shape depends on casting machine used .
Modern machines use tall crucible to enable the pattern to be positioned near the end of the casting machine .
