Sodium chloride is an accelerator up to about 2% of the hemihydrates, but at a higher concentration, it acts as a retarder. Sodium sulphate has its maximum acceleration effect at approximately 3.4%; at greater concentrations, it becomes a retarder.
The most commonly used accelerator is potassium sulphate. It is particularly effective in concentrations higher than 2% since the reaction product. which seems to be syngenite (K,Ca[SO4].H1O) crystallizes rapidly. Many soluble sulphates act as accelerators, whereas powdered gypsum (calcium sulphate dehydrate) accelerates the setting rate, because the
particles act as nuclei of crystallization.
Citrates. acetates and borates generally retard the reaction.