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Dental Materials

Impression Material

 

 

Materials

Type

Reaction

Composition

Manipulation

Initial setting time

 

Plaster

Rigid

Chemical

Calcuim sulfate hemihydrate, water

Mix P/L in bowl

3-5 min

 

Compound

Rigid

Physical

Resins, wax, stearic acid, and fillers

Soften by heating

 

Variable (sets on

cooling)

Zinc oxide-eugonel

Rigid

Chemical

Zinc oxide powder, oils, eugenol, and

resin

Mix pastes on pad

 

3-5 min

 

Agar-agar

Flexible

Physical

12-15% agar, borax, potassium sulfate,

and 85% water

Mix P/L in bowl

 

Variable (sets on

cooling)

 

alginate

Flexible

Chemical

Sodium alginate, calcium sulfate, retarders,

and 85% water

Mix P/L in bowl

 

4-5 min

 

Polysulfide

Flexible

Chemical

Low MW mercaptan polymer, fillers, lead

dioxide, copper hydroxide, or peroxides

Mix pastes on pad

 

5-7 min

 

Silicone

Flexible

Chemical

Hydroxyl functional dimethyl siloxane, fillers,

tin octoate, and orthoethyl silicate

Mix pastes on pad

 

4.5 min

 

Polyether

Flexible

Chemical

Aromatic sulfonic acid ester and polyether

with ethylene imine groups

Mix pastes on pad

 

2-4 min

 

Polyvinyl siloxane

Flexible

Chemical

Vinyl silicone, filler, chloroplatinic acid,

low MW silicone, and filler

Mix putty or use

two-component

mixing gun

 

4-5 min

 

 

 

 

The Sprue :

Its a channel through which molten alloy can reach the mold in an invested ring after the wax has been eliminated. Role of a Sprue: Create a channel to allow the molten wax to escape from the mold. Enable the molten alloy to flow into the mold which was previously occupied by the wax pattern.

FUNCTIONS OF SPRUE

1 . Forms a mount for the wax pattern .
2 . Creates a channel for elimination of wax .
3 .Forms a channel for entry of molten metal
4 . Provides a reservoir of molten metal to compensate for the alloy shrinkage .

SELECTION OF SPRUE

Sprue former gauge selection is often empirical, is yet based on the following five general principles:
1.   Select the gauge sprue former with a diameter that is approximately the same size as the thickest area of the wax pattern. If the pattern is small, the sprue former must also be small because a large sprue former attached to a thin delicate pattern could cause distortion. However if the sprue former diameter is too small this area will solidify before the casting itself and localized shrinkage porosity may result.
2.   If possible the sprue former should be attached to the portion of the pattern with the largest cross-sectional area. It is best for the molten alloy to flow from the thick section to the surrounding thin areas. This design minimizes the risk of turbulence.
3.   The length of the sprue former should be long enough to properly position the pattern in the casting ring within 6mm of the trailing end and yet short enough so the molten alloy does not solidify before it fills the mold.
4.   The type of sprue former selected influences the burnout technique used. It is advisable to use a two-stage burnout technique whenever plastic sprue formers or patterns are involved to ensure complete carbon elimination, because plastic sprues soften at temperatures above the melting point of the inlay waxes.
5.   Patterns may be sprued directly or indirectly. For direct sprueing the sprue former provides the direct connection between the pattern area and the sprue base or crucible former area. With indirect spruing a connector or reservoir bar is positioned between the pattern and the crucible former. It is common to use indirect spruing for multiple stage units and fixed partial dentures.

Tooth Polishing and Cleansing Agents

1. Cleansing-removal of exogenous stains, pellicle, materia alba, and other oral debris without causing undue abrasion to tooth structure
2. Polishing-smoothening surfaces of amalgam, composite, glass ionomers, porcelain, and other restorative materials


Factors influencing cleaning and polishing

-    Hardness of abrasive particles versus substrate
-    Particle size of abrasive particles
-    Pressure applied during procedure
-  Temperature of abrasive materials

Structure

 Composition

-contain abrasives, such as kaolinite, silicon dioxide, calcined magnesium silicate, diatomaceous silicon dioxide, pumice. Sodium-potassium
-aluminum silicate, or zirconium silicate; some pastes also may contain sodium fluoride or stannous fluoride, but they have never been shown to produce positive effects
 

Reactions-abrasion for cleansing and polishing

Properties -  Mechanical
 

- Products with pumice and quartz produce more efficient cleansing but also generate greater abrasion of enamel and dentin
-Coarse pumice is the most abrasive
-The abrasion rate of dentin is 5 to 6 times faster than the abrasion rate of enamel, regardless of the product
-Polymeric restorative materials, such as denture bases, denture teeth, composites, PMMA veneers, and composite veneers, can be easily scratched during polishing
-Do not polish cast porcelain restorations (e.g., Dicor) that are  externally characterized or the color will be lost
 

Classification of Dental amalgam

1. By powder particle shape .

  • Irregular (comminuted, filing, or lathecut)
  • Spherical (spherodized)
  • Blends (e.g., irregular-irregular, irregularspherical, or spherical-spherical)

2. By total amount of copper

  • Low-copper alloys (e.g., conventional, traditional); <5% copper
  • High-copper alloys (e,g.  corrosion resistant); 12% to 28% copper

3.By presence of zinc

Examples

  • Low-copper, irregular-particle alloy-silver (70%)-tin (26%)-copper (4%)
  • High-copper, blended-particles alloy-irregular particles, silver (70%) –tin (26%) -Copper (4%); spherical particles, silver (72%)-copper (28%)
  • High-copper, spherical-particles alloy-silver (60%) - tin (27%)-copper (13%)

Mercury bioactivity

  • Metallic mercury is the least toxic from and is absorbed primarily through the lungs rather than the GI tract or skin
  • Mercury in the body may come from air, water, food. dental (a low amount). Or medical sources
  •  Half life for mercury elimination from body is 55 days .-
  • mercury toxicity is <50 µm / m3 on average per 40-hour work week.
  • Mercury hypersensitivity is estimated as less than 1 per 100,000,000 persons
  • Indium-containing amalgams can have lower Hg vapor pressures than conventional dental amalgam

Structure of gypsum products

Components
 

a. Powder (calcium sulfate hemihydrate = CaSO4½H2O)
b. Water (for reaction with powder and dispersing powder)

Casting ring

CASTING RING LINERS

Most common way to provide investment expansion is by using a liner in the casting ring .Traditionally asbestose was used .
Non asbestose ring liner used are :
1) Aluminosilicate ceramic liner .
2) Cellulose paper liner .

The aim of using a resilient liner is to

-. allow different types of investmentbexpansion (act as a cushion)
_. facilitate venting during casting procedure.
_. facilitate the removal of the investment block after casting.&. prevent the distortion by permitting the outward expansion of the mold.
The casting ring holds the investment in place during setting and restricts the expansion of the mold. Normally a resilient liner is placed inside the ring leaving about 2-3 mm from both ends to allow for supporting contact of the investment with the casting ring.

Purpose of Casting Ring Liner

Ringer liner is he most commonly used technique to provide investment expansion. To ensure uniform expansion , liner is cut to fit the inside diameter of the casting ring with no overlap. 

Non-asbestos Ring Liners: Ceramic (aluminum silicate) Cellulose (paper) Ceramic-cellulose combination Safety of the ceramic ring liners remains uncertain, because aluminum silicate also appears capable of producing hazardous-size respirable particles
 

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