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Dental Materials

Properties of Acrylic Resins.

  • They have a low thermal conductivity. These resins are not easily washed out by the acids of the oral cavity (low solubility). Acrylic resins are also resilient, which allows them to be used in stress-bearing areas.
  • Acrylic resins exhibit a moderate shrinkage of from 3 to 8 percent. This shrinkage and low marginal strength can lead to marginal leakage. Acrylic resins have a low resistance to wear. Acrylic resins cannot be used over a zinc oxide and eugenol-type base because eugenol interferes with the acrylic curing process.
  • Mixing. Insufficient mixing will cause an uneven color or streaks in the mixture. Overmixing will cause the material to harden before it can be placed
  • Poor distortion resistance at higher temperatures, therefore dentures should not be cleaned in hot water
  • Good resistance to color change
  • Absorbs water and must be kept hydrated  (stored in water when not in mouth) to prevent dehydration cycling and changes in dimensions
  • Not resistant to strong oxidizing agents
  • Low strength; however, flexible, with good fatigue resistance
  • Poor scratch resistance; clean tissue-bearing surfaces of denture with soft brush and do not use abrasive cleaners

Casting ring

CASTING RING LINERS

Most common way to provide investment expansion is by using a liner in the casting ring .Traditionally asbestose was used .
Non asbestose ring liner used are :
1) Aluminosilicate ceramic liner .
2) Cellulose paper liner .

The aim of using a resilient liner is to

-. allow different types of investmentbexpansion (act as a cushion)
_. facilitate venting during casting procedure.
_. facilitate the removal of the investment block after casting.&. prevent the distortion by permitting the outward expansion of the mold.
The casting ring holds the investment in place during setting and restricts the expansion of the mold. Normally a resilient liner is placed inside the ring leaving about 2-3 mm from both ends to allow for supporting contact of the investment with the casting ring.

Purpose of Casting Ring Liner

Ringer liner is he most commonly used technique to provide investment expansion. To ensure uniform expansion , liner is cut to fit the inside diameter of the casting ring with no overlap. 

Non-asbestos Ring Liners: Ceramic (aluminum silicate) Cellulose (paper) Ceramic-cellulose combination Safety of the ceramic ring liners remains uncertain, because aluminum silicate also appears capable of producing hazardous-size respirable particles
 

Mercury hygiene

  • Do not contact mercury with skin
  • Clean up spills to minimize mercury vaporization
  • Store mercury or precapsulated products in tight containers
  • Only triturate amalgam components-in tightly- sealed capsules
  • Use amalgam with covers
  • Store spent amalgam under water or fixer in a tightly sealed jar
  • Use high vacuum suction during amalgam alloy placement, setting, or removal when mercury may be vaporized
  • Polishing amalgams generally causes localized melting of silver-mercury phase with release of mercury vapor, so water cooling and evacuation must be used

Classification of Dental amalgam

1. By powder particle shape .

  • Irregular (comminuted, filing, or lathecut)
  • Spherical (spherodized)
  • Blends (e.g., irregular-irregular, irregularspherical, or spherical-spherical)

2. By total amount of copper

  • Low-copper alloys (e.g., conventional, traditional); <5% copper
  • High-copper alloys (e,g.  corrosion resistant); 12% to 28% copper

3.By presence of zinc

Examples

  • Low-copper, irregular-particle alloy-silver (70%)-tin (26%)-copper (4%)
  • High-copper, blended-particles alloy-irregular particles, silver (70%) –tin (26%) -Copper (4%); spherical particles, silver (72%)-copper (28%)
  • High-copper, spherical-particles alloy-silver (60%) - tin (27%)-copper (13%)

Casting of glass or ceramic

A castable ceramic is prepared in a similar manner as metal cast preparation .
Glass is heated to 1360 degrees & then cast.
Phosphate bonded investments are used for this purpose .

Investment Materials

Investment is mold-making material

Applications

a. Mold-making materials for casting alloys
b. Mold-making materials for denture production

Classification

a. Gypsum-bonded investments (based on gypsum products for matrix)

b. Phosphate-bonded investments

c. Silicate-bonded investments

Components

a. Liquid-water or other reactant starts formation of matrix binder by reacting with reactant powder
b. Powder-reactant powder, filler, or modifiers

Manipulation

a. P/L mixed and placed in container around wax pattern
b. After setting, the investment is heated to eliminate the wax pattern in preparation for casting
 

Structure of gypsum products

Components
 

a. Powder (calcium sulfate hemihydrate = CaSO4½H2O)
b. Water (for reaction with powder and dispersing powder)

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