NEET MDS Lessons
Dental Materials
Solution Liners (Varnishes)
Applications
o Enamel and dentin lining for amalgam restorations
o Enamel and dentin lining for cast restorations that are used with non adhesive cements
o Coating over materials that are moisture sensitive during setting
Components of copal resin varnish
o 90% solvent mixture (e.g., chloroform, acetone, and alcohol)
o 10% dissolved copal resin
Reaction
Varnish sets physically by drying Solvent loss occurs in 5 to 15 seconds (a film forms the same way as drying fingernail polish)
Manipulation
Apply thin coat over dentin. enamel. And margins of the cavity preparation Dry lightly with air for 5 seconds Apply a second thin coat Final thickness is 1 to 5 µ.m
Properties
o Physical
Electrically insulating barrier that prevents shocks. Too thin to be thermally insulating. Decreases degree of percolation attributable to thermal expansion
o Chemical
Forms temporary barrier that prevents microleakage into dentinal tubules until secondary dentin formation occurs. Decreases initial tendency for electrochemical corrosion
o Mechanical
Very weak and brittle film that has limited lifetime
Film adheres to smear layer
Properties
I. Physical
a. Excellent thermal and electrical insulator
b. Very dense
c. Excellent dimensional stability
d. Good reproduction of fine detail of hard and soft tissues
2. Chemical
a. Heating will reverse the reaction (decompose the material into calcium sulfate hemihydrate, the original dry component)
b. Models, casts, and dies should be wet during grinding or cutting operations to prevent heating
3. Mechanical
a. Better powder packing and lower water contents at mixing lead to higher compressive strengths (plaster < stone < diestone)
b. Poor resistance to abrasion
4. Biologic
a. Materials are safe for contact with external - epithelial tissues
b. Masks should be worn during grinding or polishing operations that are likely to produce gypsum dust
Waxes
Many different waxes are used in dentistry. The composition, form, and color of each wax are designed to facilitate its use and to produce the best possible results.
Applications
o Making impressions
o Registering of tooth or soft tissue positions
o Creating restorative patterns for lab fabrication
o Aiding in laboratory procedures
Classification
a. Pattern waxes-inlay, casting, and baseplate waxes
b. Impression waxes-corrective and biteplate waxes
c. Processing waxes-boxing, utility, and sticky waxes
Types
1) Inlay wax-used to create a pattern for inlay, onlay or crown for subsequent investing and casting in a metal alloy.
2) Casting wax-used to create a pattern for metallic framework for a removable partial denture
3) Baseplate wax-used to establish the vertical dimension. plane of occlusion. and initial arch form of a complete denture
4) Corrective impression wax-used to form a registry pattern of soft tissues on an impression
5) Bite registration wax-used to form a registry pattern for the occlusion of opposing models or casts
6) Boxing wax-used to form a box around an impression before pouring a model or cast
7) Utility wax -soft pliable adhesive wax for modifying appliances, such as alginate impression trays
8) Sticky wax-sticky when melted and used to temporarily adhere pieces of metal or resin in laboratory procedures
Components
a. Base waxes-hydrocarbon (paraffin) ester waxes
b. Modifier waxes-carnauba, ceresin, bees wax, rosin, gum dammar, or microcrystalline waxes
c. Additives-colorants
Reaction-waxes are thermoplastic
Properties
Physical
a. High coefficients of thermal expansion and contraction
b. Insulators and so, cool unevenly; should be waxed in increments to allow heat dissipation
Chemical
a. Degrade prematurely if overheated
b. Designed to degrade into CO2and H2Oduring burnout
Mechanical-stiffness, hardness, and strength depend on modifier waxes used
Finishing and Polishing
Remove oxygen-inhibited layer .Use stones or carbide burs for gross reduction.Use highly fluted carbide burs or special diamonds for fine reduction.Use aluminum oxide strips or disks for finishing. Use fine aluminum oxide finishing pastes. Microfills develop smoothest finish because of small size of filler particles
Physical reaction-cooling causes reversible hardening
Chemical reaction-irreversible reaction during setting
COMPOSITE RESINS
Reaction
- Free radical polymerization
Monomers + initiator. + accelerators-+ polymer molecules
- Initiators-start polymerization by decomposing and reacting with monomer
- Accelerators-speed up initiator decomposition
- Amines used for accelerating self –curing systems
- Light used for accelerating light-curing systems
Retarders or inhibitors-prevent premature polymerization
COMPOSITE RESINS
Types
- Amount of filler-25% to 65% volume, 45% to 85% weight
- Filler particle size (diameter in microns)
- Macrofill 10 to 100 µm (traditional composites)
- Midi fill- 1 to 10 µm(small particle composites)
- Minifill— 0.l to 1 µm
- Microfill-: 0.01 to 0.1 µm (fine particle composites)
- Hybrid--blend (usually or microfill and midifill or minifill and microfill)
- Polymerization method
- Auto-cured (self-cured)
- Visible light cured
- Dual cured
- Staged cure
- Matrix chemistry
- BIS-GMA type
- Urethane dimethacrylate (UDM or UDMA) type
- TEGDMA-diluent monomer to reduce viscosity