Surface Preparation for Mechanical Bonding

Methods for Producing Surface Roughness

• Grinding and Etching: The common methods for creating surface roughness to enhance mechanical bonding include grinding or etching the surface.
  • Grinding: This method produces gross mechanical roughness but leaves a smear layer of hydroxyapatite crystals and denatured collagen approximately 1 to 3 µm thick.
  • Etching: Etching can remove the smear layer and create a more favorable surface for bonding.

Importance of Surface Preparation

• Proper surface preparation is critical for achieving effective mechanical bonding between dental materials, ensuring the longevity and success of restorations.

Light-Cure Composites

Light-cure composites are resin-based materials that harden when exposed to specific wavelengths of light. They are widely used in dental restorations due to their aesthetic properties, ease of use, and ability to bond to tooth structure.

Key Components:

• Diketone Photoinitiator: The primary photoinitiator used in light-cure composites is camphoroquinone. This compound plays a crucial role in the polymerization process.
• Visible Light Spectrum: The curing process is activated by blue light, typically in the range of 400-500 nm.

2. Curing Lamps: Halogen Bulbs and QTH Lamps

Halogen Bulbs

• Efficiency: Halogen bulbs maintain a constant blue light efficiency for approximately 100 hours under normal use. This consistency is vital for reliable curing of dental composites.
• Step Curing: Halogen lamps allow for a technique known as step curing, where the composite is first cured at a lower energy level and then stepped up to higher energy levels. This method can enhance the properties of the cured material.

Quartz Tungsten Halogen (QTH) Curing Lamps

• Irradiance Requirements: To adequately cure a 2 mm thick specimen of resin-based composite, an irradiance value of at least 300 mW/cm² to 400 mW/cm² is necessary. This ensures that the light penetrates the composite effectively.
• Micro-filled vs. Hybrid Composites: Micro-filled composites require twice the irradiance value compared to hybrid composites. This is due to their unique composition and light transmission properties.

3. Mechanism of Visible Light Curing

The curing process involves several key steps:

Photoinitiation

• Absorption of Light: When camphoroquinone absorbs blue light in the 400-500 nm range, it becomes excited and forms free radicals.
• Free Radical Formation: These free radicals are essential for initiating the polymerization process, leading to the hardening of the composite material.

Polymerization

• Chain Reaction: The free radicals generated initiate a chain reaction that links monomers together, forming a solid polymer network.
• Maximum Absorption: The maximum absorption wavelength of camphoroquinone is at 468 nm, which is optimal for effective curing.

4. Practical Considerations in Curing

Curing Depth

• The depth of cure is influenced by the type of composite used, the thickness of the layer, and the irradiance of the light source. It is crucial to ensure that the light penetrates adequately to achieve a complete cure.

Operator Technique

• Proper technique in positioning the curing light and ensuring adequate exposure time is essential for achieving optimal results. Inadequate curing can lead to compromised mechanical properties and increased susceptibility to wear and staining.

Glass ionomer cement is a tooth coloured material 
Material was based on reaction between silicate glass powder & polyacrylicacid.
They bond chemically to tooth structure & release fluoride for relatively long period

CLASSIFICATION 

Type I. For luting

Type II. For restoration 

Type II.1 Restorative esthetic 

Type II.2 Restorative reinforced

Type III. For liner & bases

Type IV. Fissure & sealent

Type V. As Orthodontic cement

Type VI. For core build up

Physical Properties

1. Low solubility
2. Coefficient of thermal expansion similar to dentin
3. Fluoride release and fluoride recharge
4. High compressive strengths
5. Bonds to tooth structure
6. Low flexural strength
7. Low shear strength
8. Dimensional change (slight expansion) (shrinks on setting, expands with water sorption)
9. Brittle
10.Lacks translucency
11.Rough surface texture

Indications for use of Type II glass ionomer cements 

1) non-stress bearing areas 

2) class III and V restorations in adults 

3) class I and II restorations in primary dentition 

4) temporary or “caries control” restorations 

5) crown margin repairs 

6) cement base under amalgam, resin, ceramics, direct and indirect gold 

7) core buildups when at least 3 walls of tooth are remaining (after crown preparation)

Contraindications 

1) high stress applications I. class IV and class II restorations II. cusp replacement III. core build-ups with less than 3 sound walls remaining

Composition

Factors affecting the rate or setting

1. Glass composition:Higher Alumina – Silica ratio, faster set and shorter working time.
2. Particle Size: finer the powder, faster the set.
3. Addition of Tartaric Acid:-Sharpens set without shortening the working time.
4. Relative proportions of the constituents: Greater the proportion of glass and lower the proportion of water, the faster the set.
5. Temperature

Setting Time

Type 1 - 4-5 min
type II - 7 min

PROPERTIES 

Adhesion :

- Glass ionomer cement bonds chemically to the tooth structure->reaction occur between carboxyl group of poly acid & calcium of hydroxyl apatite.
 
- Bonding with enamel is higher than that of dentin ,due to greater inorganic content. 

Esthetics :
-GIC is tooth coloured material & available in different shades.
Inferior to composites.
They lack translucency & rough surface texture.
Potential for discolouration & staining.

Biocompatibilty :

- Pulpal response to glass ionomer cement is favorable. 
- Pulpal response is mild due to 
- High buffering capacity of hydroxy apatite. 
- Large molecular weight of the polyacrylic acid ,which prevents entry into dentinal tubules. 

a) Pulp reaction – ZOE < Glass Ionomer < Zinc Phosphate 

b) Powder:liquid ratio influences acidity 

c) Solubility & Disintegration:-Initial solubility is high due to leaching of intermediate products.The complete setting reaction takes place in 24 hrs, cement should be protected from saliva during this period.

Anticariogenic properties :
- Fluoride is released from glass ionomer at the time of mixing & lies with in matrix.
Fluoride can be released out without affecting the physical properties of cement.

ADVANTAGE DISADVANTAGE

Radiographic Advancements in Caries Detection

Advancements in dental technology have significantly improved the detection and quantification of dental caries. This lecture will cover several key technologies used in caries detection, including Diagnodent, infrared and red fluorescence, DIFOTI, and QLF, as well as the film speeds used in radiographic imaging.

1. Diagnodent

• Technology:

  • Utilizes infrared laser fluorescence for the detection and quantification of dental caries, particularly effective for occlusal and smooth surface caries.
  • Not as effective for detecting proximal caries.

• Specifications:

  • Operates using red light with a wavelength of 655 nm.
  • Features a fiber optic cable with a handheld probe and a diode laser light source.
  • The device transmits light to the handheld probe and fiber optic tip.

• Measurement:

  • Scores dental caries on a scale of 0-99.
  • Fluorescence is attributed to the presence of porphyrin, a compound produced by bacteria in carious lesions.

• Scoring Criteria:

  • Score 1: <15 - No dental caries; up to half of enamel intact.
  • Score 2: 15-19 - Demineralization extends into the inner half of enamel or upper third of dentin.
  • Score 3: >19 - Extending into the inner portion of dentin.

2. Infrared and Red Fluorescence

• Also Known As: Midwest Caries I.D. detection handpiece.
• Technology:
  • Utilizes two wavelengths:
    • 880 nm - Infrared
    • 660 nm - Red
• Application:
  • Designed for use over all tooth surfaces.
  • Particularly useful for detecting hidden occlusal caries.

3. DIFOTI (Digital Imaging Fiber Optic Transillumination)

• Description:
  • An advancement of the Fiber Optic Transillumination (FOTI) technique.
• Application:
  • Primarily used for the detection of proximal caries.
• Drawback:
  • Difficulty in accurately determining the depth of the lesion.

4. QLF (Quantitative Laser Fluorescence)

• Overview:
  • One of the most extensively investigated techniques for early detection of dental caries, introduced in 1978.
• Effectiveness:
  • Good for detecting occlusal and smooth surface caries.
  • Challenging for detecting interproximal caries.

Film Speed in Radiographic Imaging

• Film Types:
  • Film D: Best film for detecting incipient caries.
  • Film E: Most commonly used film in dentistry for caries detection.
  • Film F: Most recommended film speed for general use.
  • Film C: No longer available.

Onlay Preparation

Onlay preparations are a type of indirect restoration used to restore teeth that have significant loss of structure but still retain enough healthy tooth structure to support a restoration. Onlays are designed to cover one or more cusps of a tooth and are often used when a full crown is not necessary.

1. Definition of Onlay

A. Onlay

• An onlay is a restoration that is fabricated using an indirect procedure, covering one or more cusps of a tooth. It is designed to restore the tooth's function and aesthetics while preserving as much healthy tooth structure as possible.

2. Indications for Onlay Preparation

• Extensive Caries: When a tooth has significant decay that cannot be effectively treated with a filling but does not require a full crown.
• Fractured Teeth: For teeth that have fractured cusps or significant structural loss.
• Strengthening: To reinforce a tooth that has been weakened by previous restorations or caries.

3. Onlay Preparation Procedure

A. Initial Assessment

• Clinical Examination: Assess the extent of caries or damage to determine if an onlay is appropriate.
• Radiographic Evaluation: Use X-rays to evaluate the tooth structure and surrounding tissues.

B. Tooth Preparation

1. Burs Used:

   • Commonly used burs include No. 169 L for initial cavity preparation and No. 271 for refining the preparation.

2. Cavity Preparation:

   • Occlusal Entry: The initial occlusal entry should be approximately 1.5 mm deep.
   • Divergence of Walls: All cavity walls should diverge occlusally by 2-5 degrees:
     • 2 degrees: For short vertical walls.
     • 5 degrees: For long vertical walls.

3. Proximal Box Preparation:

   • The proximal box margins should clear adjacent teeth by 0.2-0.5 mm, with 0.5 ± 0.2 mm being ideal.

C. Bevels and Flares

1. Facial and Lingual Flares:

   • Primary and secondary flares should be created on the facial and lingual proximal walls to form the walls in two planes.
   • The secondary flare widens the proximal box, allowing for better access and cleaning.

2. Gingival Bevels:

   • Should be 0.5-1 mm wide and blend with the secondary flare, resulting in a marginal metal angle of 30 degrees.

3. Occlusal Bevels:

   • Present on the cavosurface margins of the cavity on the occlusal surface, approximately 1/4th the depth of the respective wall, resulting in a marginal metal angle of 40 degrees.

4. Dimensions for Onlay Preparation

A. Depth of Preparation

• Occlusal Depth: Approximately 1.5 mm to ensure adequate thickness of the restorative material.
• Proximal Box Depth: Should be sufficient to accommodate the onlay while maintaining the integrity of the tooth structure.

B. Marginal Angles

• Facial and Lingual Margins: Should be prepared with a 30-degree angle for burnishability and strength.
• Enamel Margins: Ideally, the enamel margins should be blunted to a 140-degree angle to enhance strength.

C. Cusp Reduction

• Cusp Coverage: Cusp reduction is indicated when more than 1/2 of a cusp is involved, and mandatory when 2/3 or more is involved.
• Uniform Metal Thickness: The reduction must provide for a uniform metal thickness of approximately 1.5 mm over the reduced cusps.
• Facial Cusp Reduction: For maxillary premolars and first molars, the reduction of the facial cusp should be 0.75-1 mm for esthetic reasons.

D. Reverse Bevel

• Definition: A bevel on the margins of the reduced cusp, extending beyond any occlusal contact with opposing teeth, resulting in a marginal metal angle of 30 degrees.

5. Considerations for Onlay Preparation

• Retention and Resistance: The preparation should be designed to maximize retention and resistance form, which may include the use of proximal retentive grooves and collar features.
• Aesthetic Considerations: The preparation should account for the esthetic requirements, especially in anterior teeth or visible areas.
• Material Selection: The choice of material (e.g., gold, porcelain, composite) will influence the preparation design and dimensions.

_{Electrochemical Corrosion}

_{Electrochemical corrosion is a significant phenomenon that can affect the longevity and integrity of dental materials, particularly in amalgam restorations. Understanding the mechanisms of corrosion, including the role of electromotive force (EMF) and the specific reactions that occur at the margins of restorations, is essential for dental clinics}

_{1. Electrochemical Corrosion and Creep}

_{A. Definition}

• _{Electrochemical Corrosion: This type of corrosion occurs when metals undergo oxidation and reduction reactions in the presence of an electrolyte, leading to the deterioration of the material.}

_{B. Creep at Margins}

• _{Creep: In the context of dental amalgams, creep refers to the slow, permanent deformation of the material at the margins of the restoration. This can lead to the extrusion of material at the margins, compromising the seal and integrity of the restoration.}

_{C. Mercuroscopic Expansion}

• _{Mercuroscopic Expansion: This phenomenon occurs when mercury from the amalgam (specifically from the Sn7-8 Hg phase) reacts with Ag3Sn particles. The reaction produces further expansion, which can exacerbate the issues related to creep and marginal integrity.}

_{2. Electromotive Force (EMF) Series}

_{A. Definition}

• _{Electromotive Force (EMF) Series: The EMF series is a classification of elements based on their tendency to dissolve in water. It ranks metals according to their standard electrode potentials, which indicate how easily they can be oxidized.}

_{B. Importance in Corrosion}

• _{Dissolution Tendencies: The EMF series helps predict which metals are more likely to corrode when in contact with other metals or electrolytes. Metals higher in the series have a greater tendency to lose electrons and dissolve, making them more susceptible to corrosion.}

_{C. Calculation of Potential Values}

• _{Standard Conditions: The potential values in the EMF series are calculated under standard conditions, specifically:}
  • _{One Atomic Weight: Measured in grams.}
  • _{1000 mL of Water: The concentration of ions is considered in a liter of water.}
  • _{Temperature: Typically at 25°C (298 K).}

_{3. Implications for Dental Practice}

_{A. Material Selection}

• _{Understanding the EMF series can guide dental professionals in selecting materials that are less prone to corrosion when used in combination with other metals, such as in restorations or prosthetics.}

_{B. Prevention of Corrosion}

• _{Proper Handling: Careful handling and placement of amalgam restorations can minimize the risk of electrochemical corrosion.}
• _{Avoiding Dissimilar Metals: Reducing the use of dissimilar metals in close proximity can help prevent galvanic corrosion, which can occur when two different metals are in contact in the presence of an electrolyte.}

_{C. Monitoring and Maintenance}

• _{Regular monitoring of restorations for signs of marginal breakdown or corrosion can help in early detection and intervention, preserving the integrity of dental work.}