Caridex System

Caridex is a dental system designed for the treatment of root canals, utilizing the non-specific proteolytic effects of sodium hypochlorite (NaOCl) to aid in the cleaning and disinfection of the root canal system. Below is an overview of its components, mechanism of action, advantages, and drawbacks.

1. Components of Caridex

A. Caridex Solution I

• Composition:
  • 0.1 M Butyric Acid
  • 0.1 M Sodium Hypochlorite (NaOCl)
  • 0.1 M Sodium Hydroxide (NaOH)

B. Caridex Solution II

• Composition:
  • 1% Sodium Hypochlorite in a weak alkaline solution.

C. Delivery System

• Components:
  • NaOCl Pump: Delivers the sodium hypochlorite solution.
  • Heater: Maintains the temperature of the solution for optimal efficacy.
  • Solution Reservoir: Holds the prepared solutions.
  • Handpiece: Designed to hold the applicator tip for precise application.

2. Mechanism of Action

• Proteolytic Effect: The primary mechanism of action of Caridex is based on the non-specific proteolytic effect of sodium hypochlorite.
• Chlorination of Collagen: The N-monochloro-dl-2-aminobutyric acid (NMAB) component enhances the chlorination of degraded collagen in dentin.
• Conversion of Hydroxyproline: The hydroxyproline present in collagen is converted to pyrrole-2-carboxylic acid, which is part of the degradation process of dentin collagen.

3. pH and Application Time

• Resultant pH: The pH of the Caridex solution is approximately 12, which is alkaline and conducive to the disinfection process.
• Application Time: The recommended application time for Caridex is 20 minutes, allowing sufficient time for the solution to act on the root canal system.

4. Advantages

• Effective Disinfection: The use of sodium hypochlorite provides a strong antimicrobial effect, helping to eliminate bacteria and debris from the root canal.
• Collagen Degradation: The system's ability to degrade collagen can aid in the removal of organic material from the canal.

5. Drawbacks

• Low Efficiency: The overall effectiveness of the Caridex system may be limited compared to other modern endodontic cleaning solutions.
• Short Shelf Life: The components may have a limited shelf life, affecting their usability over time.
• Time and Volume: The system requires a significant volume of solution and a longer application time, which may not be practical in all clinical settings.

Proper Pin Placement in Amalgam Restorations

Principles of Pin Placement

• Strength Maintenance: Proper pin placement does not reduce the strength of amalgam restorations. The goal is to maintain the strength of the restoration regardless of the clinical problem, tooth size, or available space for pins.
• Single Unit Restoration: In modern amalgam preparations, it is essential to secure the restoration and the tooth as a single unit. This is particularly important when significant tooth structure has been lost.

Considerations for Cusp Replacement

• Cusp Replacement: If the mesiofacial wall is replaced, the mesiofacial cusp must also be replaced to ensure proper occlusal function and distribution of forces.
• Force Distribution: It is crucial to recognize that forces of occlusal loading must be distributed over a large area. If the distofacial cusp were replaced with a pin, there would be a tendency for the restoration to rotate around the mesial pins, potentially leading to displacement or failure of the restoration.

Mercury Release in Dental Procedures Involving Amalgam

Mercury is a key component of dental amalgam, and its release during various dental procedures has been a topic of concern due to potential health risks. Understanding the amounts of mercury released during different stages of amalgam handling is essential for dental professionals to implement safety measures and minimize exposure.

1. Mercury Release Quantification

A. Trituration

• Amount Released: 1-2 µg
• Description: Trituration is the process of mixing mercury with alloy particles to form a homogenous amalgam. During this process, small amounts of mercury can be released into the air, which can contribute to overall exposure.

B. Placement of Amalgam Restoration

• Amount Released: 6-8 µg
• Description: When placing an amalgam restoration, additional mercury may be released due to the manipulation of the material. This includes the handling and packing of the amalgam into the cavity preparation.

C. Dry Polishing

• Amount Released: 44 µg
• Description: Dry polishing of amalgam restorations generates the highest amount of mercury release among the listed procedures. The friction and heat generated during dry polishing can vaporize mercury, leading to increased exposure.

D. Wet Polishing

• Amount Released: 2-4 µg
• Description: Wet polishing, which involves the use of water to cool the restoration during polishing, results in significantly lower mercury release compared to dry polishing. The water helps to capture and reduce the amount of mercury vapor released into the air.

ORMOCER (Organically Modified Ceramic)

ORMOCER is a modern dental material that combines organic and inorganic components to create a versatile and effective restorative option. Introduced as a dental restorative material in 1998, ORMOCER has gained attention for its unique properties and applications in dentistry.

1. Composition of ORMOCER

ORMOCER is characterized by a complex structure that includes both organic and inorganic networks. The main components of ORMOCER are:

A. Organic Molecule Segments

• Methacrylate Groups: These segments form a highly cross-linked matrix, contributing to the material's strength and stability.

B. Inorganic Condensing Molecules

• Three-Dimensional Networks: The inorganic components are formed through inorganic polycondensation, creating a robust backbone for the ORMOCER molecules. This structure enhances the material's mechanical properties.

C. Fillers

• Additional Fillers: Fillers are incorporated into the ORMOCER matrix to improve its physical properties, such as strength and wear resistance.

2. Properties of ORMOCER

ORMOCER exhibits several advantageous properties that make it suitable for various dental applications:

1. Biocompatibility: ORMOCER is more biocompatible than conventional composites, making it a safer choice for dental restorations.

2. Higher Bond Strength: The material demonstrates superior bond strength, enhancing its adhesion to tooth structure and restorative materials.

3. Minimal Polymerization Shrinkage: ORMOCER has the least polymerization shrinkage among resin-based filling materials, reducing the risk of gaps and microleakage.

4. Aesthetic Qualities: The material is highly aesthetic and can be matched to the natural color of teeth, making it suitable for cosmetic applications.

5. Mechanical Strength: ORMOCER exhibits high compressive strength (410 MPa) and transverse strength (143 MPa), providing durability and resistance to fracture.

3. Indications for Use

ORMOCER is indicated for a variety of dental applications, including:

1. Restorations for All Types of Preparations: ORMOCER can be used for direct and indirect restorations in various cavity preparations.

2. Aesthetic Veneers: The material's aesthetic properties make it an excellent choice for fabricating veneers that blend seamlessly with natural teeth.

3. Orthodontic Bonding Adhesive: ORMOCER can be utilized as an adhesive for bonding orthodontic brackets and appliances to teeth.

Glass ionomer cement is a tooth coloured material 
Material was based on reaction between silicate glass powder & polyacrylicacid.
They bond chemically to tooth structure & release fluoride for relatively long period

CLASSIFICATION 

Type I. For luting

Type II. For restoration 

Type II.1 Restorative esthetic 

Type II.2 Restorative reinforced

Type III. For liner & bases

Type IV. Fissure & sealent

Type V. As Orthodontic cement

Type VI. For core build up

Physical Properties

1. Low solubility
2. Coefficient of thermal expansion similar to dentin
3. Fluoride release and fluoride recharge
4. High compressive strengths
5. Bonds to tooth structure
6. Low flexural strength
7. Low shear strength
8. Dimensional change (slight expansion) (shrinks on setting, expands with water sorption)
9. Brittle
10.Lacks translucency
11.Rough surface texture

Indications for use of Type II glass ionomer cements 

1) non-stress bearing areas 

2) class III and V restorations in adults 

3) class I and II restorations in primary dentition 

4) temporary or “caries control” restorations 

5) crown margin repairs 

6) cement base under amalgam, resin, ceramics, direct and indirect gold 

7) core buildups when at least 3 walls of tooth are remaining (after crown preparation)

Contraindications 

1) high stress applications I. class IV and class II restorations II. cusp replacement III. core build-ups with less than 3 sound walls remaining

Composition

Factors affecting the rate or setting

1. Glass composition:Higher Alumina – Silica ratio, faster set and shorter working time.
2. Particle Size: finer the powder, faster the set.
3. Addition of Tartaric Acid:-Sharpens set without shortening the working time.
4. Relative proportions of the constituents: Greater the proportion of glass and lower the proportion of water, the faster the set.
5. Temperature

Setting Time

Type 1 - 4-5 min
type II - 7 min

PROPERTIES 

Adhesion :

- Glass ionomer cement bonds chemically to the tooth structure->reaction occur between carboxyl group of poly acid & calcium of hydroxyl apatite.
 
- Bonding with enamel is higher than that of dentin ,due to greater inorganic content. 

Esthetics :
-GIC is tooth coloured material & available in different shades.
Inferior to composites.
They lack translucency & rough surface texture.
Potential for discolouration & staining.

Biocompatibilty :

- Pulpal response to glass ionomer cement is favorable. 
- Pulpal response is mild due to 
- High buffering capacity of hydroxy apatite. 
- Large molecular weight of the polyacrylic acid ,which prevents entry into dentinal tubules. 

a) Pulp reaction – ZOE < Glass Ionomer < Zinc Phosphate 

b) Powder:liquid ratio influences acidity 

c) Solubility & Disintegration:-Initial solubility is high due to leaching of intermediate products.The complete setting reaction takes place in 24 hrs, cement should be protected from saliva during this period.

Anticariogenic properties :
- Fluoride is released from glass ionomer at the time of mixing & lies with in matrix.
Fluoride can be released out without affecting the physical properties of cement.

ADVANTAGE DISADVANTAGE

Resin Modified Glass Ionomer Cements (RMGIs)

Resin Modified Glass Ionomer Cements (RMGIs) represent a significant advancement in dental materials, combining the beneficial properties of both glass ionomer cements and composite resins. This overview will discuss the composition, advantages, and disadvantages of RMGIs, highlighting their role in modern dentistry.

1. Composition of Resin Modified Glass Ionomer Cements

A. Introduction

• First Introduced: RMGIs were first introduced as Vitrebond (3M), utilizing a powder-liquid system designed to enhance the properties of traditional glass ionomer cements.

B. Components

• Powder: The powder component consists of fluorosilicate glass, which provides the material with its glass ionomer properties. It also contains a photoinitiator or chemical initiator to facilitate setting.
• Liquid: The liquid component contains:
  • 15 to 25% Resin Component: Typically in the form of Hydroxyethyl Methacrylate (HEMA), which enhances the material's bonding and aesthetic properties.
  • Polyacrylic Acid Copolymer: This component contributes to the chemical adhesion properties of the cement.
  • Photoinitiator and Water: These components are essential for the setting reaction and workability of the material.

2. Advantages of Resin Modified Glass Ionomer Cements

RMGIs offer a range of benefits that make them suitable for various dental applications:

1. Extended Working Time: RMGIs provide a longer working time compared to traditional glass ionomers, allowing for more flexibility during placement.

2. Control on Setting: The setting reaction can be controlled through light curing, which allows for adjustments before the material hardens.

3. Good Adaptation: RMGIs exhibit excellent adaptation to tooth structure, which helps minimize gaps and improve the seal.

4. Chemical Adhesion to Enamel and Dentin: RMGIs bond chemically to both enamel and dentin, enhancing retention and reducing the risk of microleakage.

5. Fluoride Release: Like traditional glass ionomers, RMGIs release fluoride, which can help in the prevention of secondary caries.

6. Improved Aesthetics: The resin component allows for better color matching and aesthetics compared to conventional glass ionomers.

7. Low Interfacial Shrinkage Stress: RMGIs exhibit lower shrinkage stress upon setting compared to composite resins, reducing the risk of debonding or gap formation.

8. Superior Strength Characteristics: RMGIs generally have improved mechanical properties, making them suitable for a wider range of clinical applications.

3. Disadvantages of Resin Modified Glass Ionomer Cements

Despite their advantages, RMGIs also have some limitations:

1. Shrinkage on Setting: RMGIs can experience some degree of shrinkage during the setting process, which may affect the marginal integrity of the restoration.

2. Limited Depth of Cure: The depth of cure can be limited, especially when using more opaque lining cements. This can affect the effectiveness of the material in deeper cavities.